Unraveling Unprecedented Charge Carrier Mobility through Structure Property Relationship of Four Isomers of Didodecyl[1]benzothieno[3,2-b][1]benzothiophene.

نویسندگان

  • Yusuke Tsutsui
  • Guillaume Schweicher
  • Basab Chattopadhyay
  • Tsuneaki Sakurai
  • Jean-Baptiste Arlin
  • Christian Ruzié
  • Almaz Aliev
  • Artur Ciesielski
  • Silvia Colella
  • Alan R Kennedy
  • Vincent Lemaur
  • Yoann Olivier
  • Rachid Hadji
  • Lionel Sanguinet
  • Frédéric Castet
  • Silvio Osella
  • Dmytro Dudenko
  • David Beljonne
  • Jérôme Cornil
  • Paolo Samorì
  • Shu Seki
  • Yves H Geerts
چکیده

The structural and electronic properties of four isomers of didodecyl[1]-benzothieno[3,2-b][1]benzothiophene (C12-BTBT) have been investigated. Results show the strong impact of the molecular packing on charge carrier transport and electronic polarization properties. Field-induced time-resolved microwave conductivity measurements unravel an unprecedented high average interfacial mobility of 170 cm(2) V(-1) s(-1) for the 2,7-isomer, holding great promise for the field of organic electronics.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Optical gap in herringbone and π-stacked crystals of [1]benzothieno[3,2-b]benzothiophene and its brominated derivative

CrystEngComm COMMUNICATION Bettina V. Lotsch et al. Optical gap in herringbone and π-stacked crystals of [1]benzothieno[3,2-b] benzothiophene and its brominated derivative

متن کامل

Ultra-high mobility transparent organic thin film transistors grown by an off-centre spin-coating method.

Organic semiconductors with higher carrier mobility and better transparency have been actively pursued for numerous applications, such as flat-panel display backplane and sensor arrays. The carrier mobility is an important figure of merit and is sensitively influenced by the crystallinity and the molecular arrangement in a crystal lattice. Here we describe the growth of a highly aligned meta-st...

متن کامل

320-nm Flexible Solution-Processed 2,7-dioctyl[1] benzothieno[3,2-b]benzothiophene Transistors

Flexible organic thin-film transistors (OTFTs) have received extensive attention due to their outstanding advantages such as light weight, low cost, flexibility, large-area fabrication, and compatibility with solution-processed techniques. However, compared with a rigid substrate, it still remains a challenge to obtain good device performance by directly depositing solution-processed organic se...

متن کامل

High-performance organic field-effect transistors based on single-crystalline microribbons of a two-dimensional fused heteroarene semiconductor.

A novel two-dimensional organic semiconductor material [1]benzothieno[3,2-b][1]benzothieno[2,1-b:3,4-b':6,5-b'':7,8-b''']tetra(benzothiophene) (BTBTTBT) which largely extends the scope of the π-conjugated framework of heteroarene through "H" configuration was synthesized and its thermal, optical and electrochemical properties were investigated. This 2D molecule enables the easy growth of single...

متن کامل

DFT-Assisted Polymorph Identification from Lattice Raman Fingerprinting

A combined experimental and theoretical approach, consisting of lattice phonon Raman spectroscopy and density functional theory (DFT) calculations, is proposed as a tool for lattice dynamics characterization and polymorph phase identification. To illustrate the reliability of the method, the lattice phonon Raman spectra of two polymorphs of the molecule 2,7-dioctyloxy[1]benzothieno[3,2-b]benzot...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Advanced materials

دوره 28 33  شماره 

صفحات  -

تاریخ انتشار 2016